目的 研究漾濞泡核桃Juglans sigillata青皮的化学成分。方法 采用萃取、硅胶、RP-18、MCI等柱色谱方法对漾濞泡核桃青皮的化学成分进行分离纯化, 并运用现代波谱技术(MS、¹³C-NMR、¹H-NMR)对所分离的化合物进行结构鉴定。结果 从漾濞泡核桃青皮中共分离得到11个化合物, 分别鉴定为芥子醛(1)、顺-Δ¹⁰-二十碳烯酸(2)、5α,8α-表二氧化麦角甾-6,22E-二烯-3β-醇(3)、5,8-二羟基-4-甲氧基-α-四氢萘醌(4)、核桃酮(5)、4,5-二羟基-α-四氢萘醌(6)、4,5,8-三羟基-α-四氢萘醌(7)、5-羟基-4-甲氧基-α-四氢萘醌(8)、5-羟基-2-甲氧基-1,4-萘醌(9)、柚皮素(10)和β-谷甾醇(11)。结论 从漾濞泡核桃青皮中分离得到11个化合物, 其中化合物1～2为首次从该属植物中分离得到。

Objective To investigate the chemical constituents in the green husk of Juglans sigillate. Methods The chemical constituents were isolated by silica gel, RP-₁₈, MCI column chromatographies and so on. The structures were identified on the basis of spectroscopic analysis (MS, ¹³C-NMR, ¹H-NMR). Results Eleven compounds were isolated from the extract of green husk of J. sigillate. And their structures were characterized as: sinapaldehyde (1), (Z)-10-eicosenoic acid (2), 5α,8α-epidioxyergosta-6,22E-diene-3β-ol (3), 5,8-dihydroxy-4-methoxy-α-tetralone (4), regiolone (5), 4,5-dihydroxy-α-tetralone (6), 4,5,8-trihydroxy-α-tetralone (7), 5-hydroxy-4-methoxy-α-tetralone (8), 5-hydroxy-2-methoxy-1,4-naphthoquinone (9), naringenin (10), and β-sitosterol (11). Conclusion Compounds 1—2 are isolated from the plants of Juglans Linn. for the first time.