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[摘要]
从加拿大产西洋参果中分得一种达玛烷型新三萜皂苷, 利用理化性质和波谱数据鉴定为 3β, 12β, 20(S), 24ξ, 25-五羟基达玛-3-O-β-D-吡喃葡萄糖基-(1→2)-β-D-吡喃葡萄糖苷, 命名为西洋参皂-F1(Ⅴ)。同时鉴定了4种已知达玛烷型三萜皂苷, 即人参皂苷-Rh1(Ⅵ)、人参皂苷-Rh2(Ⅶ)、人参皂苷-Rg1(Ⅷ)及人参皂苷-Rg2(Ⅸ), 均为首次从该植物果实中分离得到。
[Key word]
[Abstract]
A new triterpenoid saponin, quinquenoside F1(Ⅴ) was isolated from the fruit of Panax quinquefolius L collected in Canada. Its structure was established as 3β, 12β, 20(S), 24ξ, 25 pentahydroxy dammarane 3Oβ D glucopyranosyl (1→2) β D glucopyranoside, on the basis of chemical and spectroscopic evidences 4 known dammarane triterpenoids were also identified at the same time, i. e. ginsenoside Rh1(Ⅵ), Rh1(Ⅶ), Rg1(Ⅷ) and Rg2(Ⅸ). All of them were obtained from the fruit of this plant for the first time.
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