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[摘要]
首次从优毛铁棒锤Aconilumflavum地上部分(花、茎、叶)中分离出4个生物碱结晶。经鉴定晶Ⅰ为脱氧乌头碱(deoxyaconitine),晶Ⅱ为3-乙酰乌头碱(3-acetylaconitine),晶Ⅲ为乌头碱(aconitine),晶Ⅳ待鉴定。乌头碱的收率为0.12%(块根中乌头碱收率为0.20%),薄层层析鉴定地上部分与块根的生物碱基本一致,为开发3-乙酰乌头碱寻找了新的资源。
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[Abstract]
Four alkaloids were isolated from the flower,stem and leaf of Aco,ritum jlavum Hand-Mazz. for the first time. Three of them were identified as deoxyaconitine,3-acetylaconitine and aconitine respectively by physico-chemical constants and spectroscopic analysis. The other one needs to be identified. The yield of aconitine is 0.12%(aconitine of root is 0.20%). By TLC, alkaloids present in the flower , stem and leaf are same as that found in the root. Therefore,the aerial parts of the plant may be exploited as a new source of 3-acetyla-conitine.
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